This flexibility makes it a popular choice among professionals in fields such as construction, mining, and geology This flexibility makes it a popular choice among professionals in fields such as construction, mining, and geologyanchor drill bit.The aim of this work was to examine particularly the Degussa P25 titanium dioxide nanoparticles (P25TiO2NPs) because they are among the most employed ones in cosmetics. In fact, all kinds of titanium dioxide nanoparticles (TiO2NPs) have gained widespread commercialization over recent decades. This white pigment (TiO2NPs) is used in a broad range of applications, including food, personal care products (toothpaste, lotions, sunscreens, face creams), drugs, plastics, ceramics, and paints. The original source is abundant in Earth as a chemically inert amphoteric oxide, which is thermally stable, corrosion-resistant, and water-insoluble. This oxide is found in three different forms: rutile (the most stable and substantial form), brookite (rhombohedral), and anatase (tetragonal as rutile), of these, both rutile and anatase are of significant commercial importance in a wide range of applications [3]. Additionally, the nano-sized oxide exhibits interesting physical properties, one of them is the ability to act as semiconducting material under UV exposure. In fact, TiO2NPs are the most well-known and useful photocatalytic material, because of their relatively low price and photo-stability [4]. Although, this photoactivity could also cause undesired molecular damage in biological tissues and needs to be urgently assessed, due to their worldwide use. However, not all nanosized titanium dioxide have the same behavior. In 2007, Rampaul A and Parkin I questioned: “whether the anatase/rutile crystal form of titanium dioxide with an organosilane or dimethicone coat, a common titania type identified in sunscreens, is appropriate to use in sunscreen lotions” [5]. They also suggested that with further study, other types of functionalized titanium dioxide could potentially be safer alternatives. Later, Damiani found that the anatase form of TiO2NPs was the more photoactive one, and stated that it should be avoided for sunscreen formulations, in agreement with Barker and Branch (2008) [6,7].
Titanium dioxide A1 adopts good oxidation process, composite inorganic coating and organic treatment, and has the characteristics of excellent particle size distribution, high brightness and high weather resistance. It is recommended for high gloss and high weather resistance coatings, inks and outdoor polymer materials.
But what is titanium dioxide, exactly? Here's what you need to know about this popular food additive — including what products it's used in and whether it's safe to consume.
Apart from the cosmetics industry, the coatings and plastics industry is also expected to contribute significantly to the growth of titanium dioxide in 2023. Coatings made from titanium dioxide offer excellent hiding power, durability and weather resistance, making them ideal for outdoor applications. Demand for high-quality coatings is expected to surge as the construction and automotive industries expand. Titanium dioxide is at the forefront of providing aesthetic and protective coatings, making it an indispensable ingredient in the industry.
For research published in Archives of Toxicology in 2020, scientists fed one group of mice a solution containing titanium dioxide for one month, and compared it to those that did not receive the additive. They found “the richness and evenness of gut microbiota were remarkably decreased and the gut microbial community compositions were significantly changed” in the titanium dioxide group when compared with the control group. The tests also revealed that the titanium dioxide exposure could cause locomotor dysfunction, or mobility issues “by elevating the excitement of enteric neurons, which might spread to the brain via gut-brain communication by vagal pathway.” The researchers concluded: “These findings provide valuable insights into the novel mechanism of TiO2NP-induced neurotoxicity. Understanding the microbiota-gut-brain axis will provide the foundation for potential therapeutic or prevention approaches against TiO2NP-induced gut and brain-related disorders.”
Resumo–Este artigo discute a descoberta de litopônio fosforescente em desenhos de aquarela do artista americano John La Farge datados de entre 1890 e 1905 e a história do litopônio na indústria de pigmento no final do século XIX e início do século XX. Apesar de ter muitas qualidades desejáveis para o uso em aquarela branca ou tintas a óleo, o desenvolvimento do litopônio como um pigmento de artistas foi prejudicado por sua tendência a se escurecer na luz solar. Sua disponibilidade para e uso por parte de artistas ainda não está clara, uma vez que os catálogos comerciais dos vendedores de tintas geralmente não eram explícitos na descrição de pigmentos brancos como algo que contém litopônio. Além disso, o litopônio pode ser confundido com o branco de chumbo durante o exame visual e sua fosforescência de curta duração pode ser facilmente perdida pelo observador desinformado. O litopônio fosforescente foi documentado em apenas um outro trabalho até hoje: uma aquarela de Van Gogh. Além da história da manufatura do litopônio, o artigo detalha o mecanismo para a sua fosforescência e sua identificação auxiliada pela espectroscopia de Raman e espectrofluorimetria.
English name: Lithopone
Titanium dioxide is an inert earth mineral used as a thickening, opacifying, and sunscreen ingredient in cosmetics. It protects skin from UVA and UVB radiation and is considered non-risky in terms of of skin sensitivity. Because it is gentle, titanium dioxide is a great sunscreen active for sensitive, redness-prone skin. It’s great for use around the eyes, as it is highly unlikely to cause stinging.
According to the EFSA's Expert Panel on Food Additives and Flavorings 2021 opinion regarding titanium dioxide, it could not rule out a concern for genotoxicity from ingestion of the material based on a perceived gap in data on this risk, which serves as the basis for current ban, said a March report on the decision.
Separately, concerns have been raised about titanium dioxide impacting one's genetic code. This can be traced to a 2009 study which found that titanium dioxide nanoparticles caused DNA damage and genetic instability in mice. A 2022 study published in Food and Chemical Toxicology also raised concerns about the DNA-damaging effects of titanium dioxide as a food additive. The study noted that results evidenced a DNA-damaging effect, and added that there may also be impacts to chromosomal integrity, an indicator of cancer risk.
≥ 5 % of standard sample
The use of titanium dioxide (TiO2) in factory settings is widespread, with this versatile compound playing a crucial role in various industrial processes. TiO2 is a naturally occurring mineral that is widely used as a white pigment in paints, coatings, plastics, paper, and other products. Its ability to effectively scatter light makes it an ideal choice for creating bright, durable, and long-lasting finishes.
The ROS seemed to be endlessly produced by P25TiO2NPs upon irradiation, since the values detected after 6 h are similar to the ones after 3 h. However, the amount of vitamin B2 in the surface of the NPs proved to be enough to decrease the ROS detected even after 6 h. Statistical analysis showed a significant difference between C and A. p < 0.05
Background and overview
Globally, Iron Oxide is the second largest inorganic pigment after Titanium Dioxide and the first largest color inorganic pigment. Iron oxide pigments mainly include iron oxide red, yellow, black and brown with iron oxide as the basic material. Iron oxide yellow, also known as hydroxyl iron oxide (FeOOH), will be dehydrated and decomposed into red at about 177 ℃, so the application of ordinary iron yellow pigment in high-temperature occasions such as plastic processing and baking coatings is limited. Iron oxide yellow pigment can improve its temperature resistance through surface coating, so as to expand the application field of iron oxide yellow pigment.
The chemical formula of iron oxide yellow (also known as hydroxyl iron) is α- Fe2O3 · H2O or α- FeOOH, with needle like structure and yellow powder, is a kind of particle size less than 0.1 μ m. Iron series pigment with good dispersibility in transparent medium has strong coloring power, high covering power, insoluble in alkali and slightly soluble in ACID. Synthetic iron oxide yellow has the characteristics of light resistance, good dispersion, non-toxic, tasteless and difficult to be absorbed by human body. It is widely used in coatings, plastics, ink and pharmaceutical industry.
Physical and chemical properties and structure
1. Iron oxide yellow pigment has acid and alkali resistance, resistance to general weak and dilute acids, and is very stable in alkaline solution of any concentration.
2. Iron oxide yellow pigment has certain light resistance, heat resistance and weather resistance. Its coating color is durable and can keep the coating from being damaged in light. Iron oxide yellow pigment is stable in a certain temperature range, but beyond the limit temperature, its color begins to change, and the degree of change is more significant with the increase of temperature. Iron oxide yellow pigment is not affected by cold, heat, dry and wet weather conditions.
3. Iron oxide yellow pigment is very stable in any ambient atmosphere (such as gases containing H 2S, Co, so 2, HCl, no, etc.). And resistant to pollution, water, oil and solvent penetration, insoluble in water, mineral oil or vegetable oil.
4. Iron oxide yellow pigment has strong coloring power and high hiding power. With the decrease of pigment particle size, its coloring power is stronger.
application
Nano iron oxide yellow has the characteristics of acid resistance, alkali resistance, non toxicity and low price. It is widely used in coatings, plastics and rubber. The particle size of nano iron yellow is less than 100 nm, which makes it have some unique characteristics. When light shines on its surface, transmission and diffraction will occur, showing transparent yellow, and can strongly absorb ultraviolet rays, Therefore, it can be used as a functional pigment for the surface paint of high-grade cars, precision instruments, bicycles, motorcycles, cosmetics, food, drugs and other coloring additives.
Nano-sized P25TiO2NPs were kindly donated by Dr. Scaiano, Ottawa University (Canada). Riboflavin (vitamin B2) was from Sigma and ascorbic acid (vitamin C) and KBr (for IR pills) were from Cicarelli. Base cream for the animal experiments was purchased from Todo Droga and the LED panel was built ad hoc.